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S Sulfur-Nitrogen Compounds
- Part 10a: Compounds with Sulfur of Oxidation Number II
Engelsk Paperback
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S Sulfur-Nitrogen Compounds
- Part 10a: Compounds with Sulfur of Oxidation Number II
Engelsk Paperback

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The present volume describes acyclic Sulfur-nitrogen compounds with sulfur of the oxida­ tion number II. The first chapter deals with sulfur imide (S=NH), N-organyl-sulfur imides (S=NR, R = or­ ganyl), and metal complexes of sulfur imides. N-Organyl-sulfur imides have not been isolated, but they can be trapped, for example, by cycloaddition and stabilized by coordination to transi­ tion metals. 11 The following chapter present a detailed survey of other 8 -N compounds with one­ coordinate sulfur, e.g., dithionitrous acid (S=N-SH) and derivatives, the salts of the dithionitryl ion (1 +) ([S=N=S]+), and N-thionitroso-diorganyl-amines (S=NNR , R = organyl). Only the reac­ 2 tions of [S=N=S]+ AsF5, among the known [S=N=S]+ salts, have been extensively studied. Cycloadditions with alkenes and triple bonded compounds produce 1 ,3,2-dithiazolium salts and their derivatives. S=NN(CH )z and S=NN(C H )z form transition metal complexes. The 3 6 5 Iigand is coordinated via the S atom in a monodentate manner.
Product detaljer
Sprog:
Engelsk
Sider:
324
ISBN-13:
9783662063538
Indbinding:
Paperback
Udgave:
ISBN-10:
3662063530
Kategori:
Udg. Dato:
3 okt 2013
Længde:
0mm
Bredde:
178mm
Højde:
254mm
Forlag:
Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Oplagsdato:
3 okt 2013
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