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Angle Resolved Photoemission Spectroscopy of Delafossite Metals

Af: Veronika Sunko Engelsk Paperback

Angle Resolved Photoemission Spectroscopy of Delafossite Metals

Af: Veronika Sunko Engelsk Paperback
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This thesis describes the results of angle resolved photoemission spectroscopy experiments on delafossite oxide metals, and theoretical work explaining these observations. The study was motivated by the extraordinarily high conductivity of the non-magnetic delafossites PdCoO2 and PtCoO2, the measurement of whose electronic structure is reported and discussed. Two unexpected effects were observed in the course of the investigation; each is described and analysed in detail. Firstly, a previously unrecognised type of spectroscopic signal, allowing the non-magnetic probe of photoemission to become sensitive to spin-spin correlations, was observed in the antiferromagnetic PdCrO2. Its origin was identified as the Kondo-like coupling of itinerant and Mott insulating electrons. Furthermore, surface states exhibiting an unusually large Rashba-like spin-splitting were observed on the transition metal terminated surfaces of delafossites. The large inversion symmetry breaking energy scale, a consequence of the unusual structure of the surface layer, is identified as the origin of the effect.
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This thesis describes the results of angle resolved photoemission spectroscopy experiments on delafossite oxide metals, and theoretical work explaining these observations. The study was motivated by the extraordinarily high conductivity of the non-magnetic delafossites PdCoO2 and PtCoO2, the measurement of whose electronic structure is reported and discussed. Two unexpected effects were observed in the course of the investigation; each is described and analysed in detail. Firstly, a previously unrecognised type of spectroscopic signal, allowing the non-magnetic probe of photoemission to become sensitive to spin-spin correlations, was observed in the antiferromagnetic PdCrO2. Its origin was identified as the Kondo-like coupling of itinerant and Mott insulating electrons. Furthermore, surface states exhibiting an unusually large Rashba-like spin-splitting were observed on the transition metal terminated surfaces of delafossites. The large inversion symmetry breaking energy scale, a consequence of the unusual structure of the surface layer, is identified as the origin of the effect.
Produktdetaljer
Sprog: Engelsk
Sider: 198
ISBN-13: 9783030310899
Indbinding: Paperback
Udgave:
ISBN-10: 3030310892
Udg. Dato: 8 okt 2020
Længde: 0mm
Bredde: 155mm
Højde: 235mm
Forlag: Springer Nature Switzerland AG
Oplagsdato: 8 okt 2020
Forfatter(e): Veronika Sunko
Forfatter(e) Veronika Sunko


Kategori Kondenserede fasers fysik: væskeform og faststoffysik


ISBN-13 9783030310899


Sprog Engelsk


Indbinding Paperback


Sider 198


Udgave


Længde 0mm


Bredde 155mm


Højde 235mm


Udg. Dato 8 okt 2020


Oplagsdato 8 okt 2020


Forlag Springer Nature Switzerland AG