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Unimolecular Reactions
- A Concise Introduction
Engelsk Paperback
Unimolecular Reactions
- A Concise Introduction
Engelsk Paperback

1.279 kr
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Om denne bog
The statistical theory of unimolecular reactions is now universally known as RRKM theory. This textbook covers the basics necessary for the understanding of RRKM theory in its original and variational, phase-space and angular momentum-conserved incarnations. After a review of the Kassel quantum model and the theory of Slater, the specific-energy RRKM rate constant k(E) is derived. The argument is then extended to the angular momentum-dependent rate constant k(E,J), to non-classical effects (tunneling and non-adiabatic transition), and the general problem of angular momentum conservation. A long chapter is devoted to the counting of quantum states. The chapter on thermal systems discusses both analytical and numerical solutions and is later extended to include the variational approach and discussion of exit channel effects. Containing many problem sets and solutions, the book is targeted at graduate and advanced undergraduate students studying chemical dynamics, chemical kinetics and theoretical chemistry.
Product detaljer
Sprog:
Engelsk
Sider:
332
ISBN-13:
9780521529228
Indbinding:
Paperback
Udgave:
ISBN-10:
0521529220
Udg. Dato:
25 sep 2003
Længde:
16mm
Bredde:
250mm
Højde:
177mm
Forlag:
Cambridge University Press
Oplagsdato:
25 sep 2003
Forfatter(e):
Kategori sammenhænge