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Milestones in Microwave Chemistry

Engelsk Paperback

Milestones in Microwave Chemistry

Engelsk Paperback
Tjek vores konkurrenters priser

This book looks back on thirty-five years of microwave (MW)chemistry and explains how the application of the MW technique became anintegral part of R&D, eventually becoming recognized in industry. Further,it details how MW chemistry has undergone a dynamic development in the pastthree decades, one driven by the advent of increasingly sophisticatedprofessional MW reactors in place of the kitchen MW ovens used in earlieryears. A major part of the book shows how substitutions, esterifications,amidations, hydrolyses, alkylations, eliminations, dehydrations, condensations,cyclizations, C-C couplings and the modification of heterocycles can beperformed advantageously under MW irradiation, as the reaction times areshorter, while the selectivity and yields are higher; it also explains why inmost cases, the reactions can be performed under solvent-free conditions. MWirradiation within the sphere of organophosphorus chemistry is showcased andtypical reactions, such as the direct derivatization of phosphinic acids,alkylating esterifications, Diels-Alder reactions, the inverse Wittig-typereaction, fragmentations, the Arbuzov reaction, the synthesis ofα-hydroxyphosphonates and α-aminophosphonates (the Kabachnik-Fieldscondensation), deoxygenations and P-C coupling reactions are described under MWconditions. In closing, the advantages of MW chemistry such as faster reactionsand the possibility of simplifying the catalytic systems are addressed.

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This book looks back on thirty-five years of microwave (MW)chemistry and explains how the application of the MW technique became anintegral part of R&D, eventually becoming recognized in industry. Further,it details how MW chemistry has undergone a dynamic development in the pastthree decades, one driven by the advent of increasingly sophisticatedprofessional MW reactors in place of the kitchen MW ovens used in earlieryears. A major part of the book shows how substitutions, esterifications,amidations, hydrolyses, alkylations, eliminations, dehydrations, condensations,cyclizations, C-C couplings and the modification of heterocycles can beperformed advantageously under MW irradiation, as the reaction times areshorter, while the selectivity and yields are higher; it also explains why inmost cases, the reactions can be performed under solvent-free conditions. MWirradiation within the sphere of organophosphorus chemistry is showcased andtypical reactions, such as the direct derivatization of phosphinic acids,alkylating esterifications, Diels-Alder reactions, the inverse Wittig-typereaction, fragmentations, the Arbuzov reaction, the synthesis ofα-hydroxyphosphonates and α-aminophosphonates (the Kabachnik-Fieldscondensation), deoxygenations and P-C coupling reactions are described under MWconditions. In closing, the advantages of MW chemistry such as faster reactionsand the possibility of simplifying the catalytic systems are addressed.

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Se mere i:
Produktdetaljer
Sprog: Engelsk
Sider: 110
ISBN-13: 9783319306308
Indbinding: Paperback
Udgave:
ISBN-10: 3319306308
Kategori: Naturvidenskabens historie
Udg. Dato: 30 mar 2016
Længde: 0mm
Bredde: 155mm
Højde: 235mm
Forlag: Springer International Publishing AG
Oplagsdato: 30 mar 2016
Forfatter(e):
Forfatter(e)

Kategori Naturvidenskabens historie

ISBN-13 9783319306308

Sprog Engelsk

Indbinding Paperback

Sider 110

Udgave

Længde 0mm

Bredde 155mm

Højde 235mm

Udg. Dato 30 mar 2016

Oplagsdato 30 mar 2016

Forlag Springer International Publishing AG