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Lewis Acidic Alkali Metal and Aluminum Complexes
- Synthesis, Reactivity and Homogeneous Catalysis
Engelsk Paperback
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Lewis Acidic Alkali Metal and Aluminum Complexes
- Synthesis, Reactivity and Homogeneous Catalysis
Engelsk Paperback

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Most industrial processes for producing bulk and fine chemicals are transition metal catalyzed. Toxicity and high cost of platinum group metals are triggering the current search for sustainable catalysts. In this regard, nontoxic and earth-abundant alkali metals could become attractive alternatives. They are the most electropositive elements of the periodic table. With a single s electron in the valence shell and a low ionization enthalpy they easily form M+ ions. The vacant, low-energy orbital of the M+ ion is capable of accepting an electron pair. This Lewis acidic property can be utilized in molecular catalysis. Since alkali metal compounds easily dimerize, oligomerize or even polymerize (Scheme A.1-1), suitable ligands are crucial for the isolation of defined metal complexes in their monomeric form.

Product detaljer
Sprog:
Engelsk
Sider:
130
ISBN-13:
9783958862432
Indbinding:
Paperback
Udgave:
ISBN-10:
3958862438
Kategori:
Udg. Dato:
24 sep 2018
Længde:
9mm
Bredde:
148mm
Højde:
208mm
Forlag:
Verlag G. Mainz
Oplagsdato:
24 sep 2018
Forfatter(e):
Kategori sammenhænge