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Dzhemilev Reaction in Organic & Organometallic Synthesis

Engelsk Paperback
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Dzhemilev Reaction in Organic & Organometallic Synthesis

Engelsk Paperback

654 kr
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Om denne bog
In the last 10 to 15 years the discovery of catalytic cycloalumination, cyclomagnesiation, and ethylmagnesiation reactions of olefins, dienes and allenes with the aid of alkyl and halogen alkyl Al and Mg derivatives under the action of Ti, Zr and Co complexes to obtain new classes of cyclic and acyclic organometallics namely aluminacyclopropanes, aluminacyclopropenes, aluminacyclopentanes, aluminacyclopent-2-enes, aluminacyclopenta-2,4-dienes, magnesacyclopentanes, magnesacyclopent-2-enes, and magnesacyclopenta-2,4-dienes are among the sound achievements in the field of organic and organometallic synthesis. These reactions are considered in the world scientific literature as Dzhemilev reactions. The monograph covers the data concerned the revealed first by Professor Dzhemilev phenomenon of catalytic replacement of transition metal atoms in metallacarbocycles by non-transition metal atoms to afford the said classes of organometallic compounds (OMC) and also the history of this discovery. Modern concepts and outlooks on mechanism of these reactions as well as the structure of the key intermediates responsible for the formation of target OMC are considered.
Product detaljer
Sprog:
Engelsk
Sider:
96
ISBN-13:
9781608766833
Indbinding:
Paperback
Udgave:
ISBN-10:
1608766837
Udg. Dato:
22 maj 2010
Længde:
7mm
Bredde:
154mm
Højde:
228mm
Forlag:
Nova Science Publishers Inc
Oplagsdato:
22 maj 2010
Forfatter(e):
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